Tablets & Capsules

TC1018

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32 October 2018 Tablets & Capsules 19. C. Hauf and R. Kniep," Preparation of various tita- nium sub oxide powders by reduction of TiO2 with sili- con," Journal of Materials Science, Vol. 34, pp. 1,287- 1,292, (1999). 20. Min Li et al., "The Influence of the Bulk Reduction State on the Surface Structure and Morphology of Rutile TiO2(110) Single Crystals," J. Phys. Chem. B, Vol. 104, pp. 4,944-4,950, (2000). 21. T. Gruenwald and G. Gordon, "Oxygen diffusion in single crystals of Titanium Dioxide," J. Inorg. Nucl. Chem., Vol. 33, pp. 1,151-1,155, (1971). 22. K. Hoshino et al., "Diffusion and Point Defects in TiO2-x," J. Phys. Chem. Solid., Vol. 46, pp. 1,397-1,411, (1985). 23. P. Dennis and R. Freer, "Oxygen self-diffusion in Rutile under hydrothermal conditions," Journal of Material Science, Vol. 28, pp. 4,804-4,810, (1993). 24. J. Nowotny et al., "Chemical diffusion in metal oxides. Example of TiO2," Ionics, Vol. 12, pp. 227-243, (2006). 25. M. Radecka et al., "Ambipolar diffusion in TiO2," Solid State Ionics, Vol. 119, pp. 55-60, (1999). 26. M. Henderson, "A surface perspective on self-dif- fusion in Rutile TiO2," Surface Science, Vol. 419, pp. 174-187, (1999). 27. S. Lee et al., "The alteration of the structural prop- erties and photocatalytic activity of TiO2 following exposure to non-linear irradiation sources," Applied Catalysis B: Environmental, Vol. 44, pp. 173-184, (2003). 28. C. Langlade et al., "Characterization of titanium oxide films with Magnéli structure elaborated by a sol-gel route," Applied Surface Science, Vol. 186, pp. 145-149, (2002). 29. T. Le Mercier et al., "Structural and chemical trans- formations induced by laser impact on TiO2 and Nb2O5," J. Phys. Chem. Solids, Vol. 58, pp. 679-684, (1997). 30. S. Williams and C. Morgan, "Excimer laser print- ing of aircraft cables," ICALEO, Santa Clara, CA, (1988). 31. C. Wolf et al., "Laser marking on electrical wire insulation. Preparation and long-term stability," McDonnell Douglas Research Laboratories Report, (1990). 32. M. Chase, "NIST-JANAF Thermochemical Tables," Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, (1998). Igor Murokh develops customized plasma-treatment and laser-marking systems for the aerospace, medical-device manu- facturing, and pharmaceutical industries at Tri-Star Technol- ogies (310 536 1303, www.tri-star-technologies.com). He has been with the company since 1994 and has authored six US patents. He holds a PhD in thermophysics and molecular physics from the A.V. Luikov Heat and Mass Transfer Insti- tute of the National Academy of Sciences of Belarus. Therefore, only light-colored products can be legibly imprinted. Despite this limitation, UV lasing of TiO 2 - pigmented tablets and capsules can be a significant step toward implementing user- and environmentally friendly, clean, precise, reliable, and permanent laser-marking tech- nology in the pharmaceutical industry. T&C References 1. "Global Laser Marking Machine Market Size and Forecast, Trend Analysis 2014 to 2024," Hexa Research. 2. C. Webb, "Handbook of laser technology and applications," Vol. III, IOP, (2004). 3. I. Murokh, "Laser Marking of Consumable Articles," US patent # 6,429,889, (2002). 4. https://www.statista.com/statistics/261303/total- number-of-retail-prescriptions-filled-annually-in-the-us/. 5 . h t t p s : / / w w w . c h e m o u r s . c o m / T i t a n i u m _ Technologies/en_US/assets/downloads/Ti-Pure-for- coatings-overview.pdf. 6. M. Henderson, "A Surface Science Perspective on TiO2 Photocatalysis," Surface Science Reports, Vol. 66, pp. 185-297, (2011). 7. T. Silfast, "Laser Fundamentals," Second edition, Cambridge University Press, (2008). 8. F. Bretenaker, "Laser: 50 Years of Discoveries," WSP, (2014). 9. J. Ion, "Laser Processing of Engineering Materials," Elsevier, (2011). 10. J. Hecht, "Understanding Lasers: An Entry-Level Guide, "3rd Edition, IEEE, (2008). 11. M. Hofmann et al., "High Contrast and intact Surface - a Challenge in Laser Marking of Plastics," SPIE, Vol. 744, Lasers in Motion for Industrial Applications, pp. 156-180, (1987). 12. U. Diebold, "Surface Science of Titanium Dioxide," Surface Science Reports, Vol. 48, pp. 53-229, (2003). 13. P. Waldner and G. Eriksson, "Thermodynamic M o d e l l i n g o f t h e S y s t e m T i t a n i u m - O x y g e n , " CALPHAD, Vol. 23, pp. 189-218, (1999). 14. S. Andersson et al., "Identification of Titanium Oxides by X-Ray Powder Patterns," Acta Chem. Stand., Vol. 11, pp. 1,641-1,652, (1957). 15. R. Bartolomew and D. Frankl, "Electrical Properties of Some Titanium Oxides," Physical Review, Vol. 187, pp. 828-833, (1969). 16. Bennett et al., "STM and LEED observations of the surface structure of TiO2 (110) following crystallo- graphic shear plane formation," Physical Review B, Vol. 59, pp. 10,341-10,346, (1999). 17. L. Bursill and M. Blanchin, "Structure of Small Oxygen Vacancy Defects in Non-stoichiometric Rutile," Journal of Solid State Chemistry, Vol. 51, pp. 321-335, (1984). 18. Y. W. Chung et al., "Low Energy Electron diffrac- tion and Electron Spectroscopy Studies of the clean (110) and (100) Titanium Dioxide (Rutile) Crystal Surfaces," Surface Science, Vol. 64, pp. 588-602, (1977).

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